The California Labor Federation is governed by an executive secretary-treasurer and a president. In addition, 47 vice-presidents representing affiliated unions and central labor councils are elected by biennial convention into the executive council of the Federation.

Vice Presidents
Gary Allen
Jeremy Abrams
Gloria Alvarado
Frank Arce
Brigette Browning
Joseph Bryant
Randy Cammack
Bonnie Castillo
Dave Connolly
Ellen Crawford
Thom Davis
Robert Dean
Oscar de la Torre
Joe Duffle
Ron Espinoza
Enrique Fernandez
Kathy Finn
Jeff Freitas
David Green
Chris Hannan
Bill Hagar
Johanna Hester
David Huerta
Julie Lind
James Lindsay
Jacques Loveall
Larry Mazzola, Jr.
Michael F. Miller
Doug Moore
Charmaine Morales
David Osborne
Tia Orr
Jon Preciado
Jason Rabinowitz
Dan Reding
Sandy Reding
Brian Rice
Tamara Rubyn
David Sikorski
Robert D. Smith
Tim Steed
Julie Van Winkle
Adam Weinberger
Yvonne Wheeler
Mario Yedidia
Andrea Zinder